During the time I spent in Berkeley I had the honor to work on the beginning of the project leading to the portable system for highly sensitive multi-dimensional chemical analysis. This work included hyphenation of NMR with liquid chromatography separation using organic polymer monoliths. I have to admit, it was my first touch of NMR [...]
Generally, methacrylic acid is used as a charge-bearing agent for generation of electroosmotic flow in capillary electrochromatography. However, methacrylic acid has a significant effect on the morphology of the monolithic stationary phases based on styrene – divinylbenzene system as showed recently by group in Prague. The monolithic material prepared without methacrylic acid in the polymerization [...]
Couple of days ago, I mentioned on Chromatographer’s facebook page article by Peter Carr about speed in HPLC published in Analytical Chemistry. There are two parts in the article: (i) critical comparison of different approaches how to reach speed in HPLC and (ii) theoretical background of speed and efficiency optimization in high performance liquid chromatography. [...]
One column fits all was title of my poster presented at HPLC 2010 in Boston that described the preparation and characterization of hypercrosslinked monolithic stationary phases and their application in several chromatographic modes. We summarized poster’s results and submitted them as a paper in Journal of Chromatography A. Hypercrosslinking modification is not a new technique. [...]
Today, I would like to describe my favorite chromatographic books: from one I bought even before I (really) knew what chromatography is to one which has chapter with my name on it. Úvod do vysokoúčinné kapalinové kolonové chromatografie I am sorry to all of you who does not understand Czech language. This is my very [...]
When two do the same thing, it’s not always the same. In the last issue of LCGC North America, Ronald Majors summarized his highlights of HPLC 2010. In my HPLC 2010 flashbacks I focused exclusively on oral presentations I have attended during the meeting. Ronald Majors summarized whole symposium in a detailed and comprehensive way, [...]
Couple of days ago I wrote about September Discussion group organized by CASSS International separation science society. As I promised I made notes and I would like to share them with you now. Although I expected slightly different format of meeting (selection of few topics and their detailed discussion with the attendants) I was able [...]
As I mentioned several weeks ago, there was an international symposium on the separation science – HPLC 2010 – held in Boston last week. It was my second North American conference (together with San Francisco 2006) and third in total (plus Stockholm 2005). Allow me to summarize my remarks I made during the lectures I [...]
Georges Guiochon pointed out in his excelent reivew about monolithic stationary phases four directions from which we can expect a serious improvement in (monolithic) columns performance. High temperature chromatography High temperature chromatography, which causes a reduction in the viscosity of the mobile phase. So far, monolithic stationary phases have not yet been used at high [...]
Analytical chemist. Amateur photographer. Occasional traveler. Lazy graphoman. Wannabe entertainer. Boring moralist ...
 |
 |
 |
 |
Chromatographic articles